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Ağırlığı, Polimerizasyon Derecesi, polimerlerin fiziksel özellikleri, polimerlerin mekanik özellikleri, Polidispersite (PDI), camsı geçiş sıcaklığına molekül ağırlığının etkisi, erime...","preview":{"posterSrc":"//avatars.mds.yandex.net/get-vthumb/905276/b00c2839c9d675ce98aadda8aafe0893/564x318_1"},"target":"_self","position":"18","reqid":"1751312994907867-5927566633186481265-balancer-l7leveler-kubr-yp-vla-124-BAL","summary":{"isFull":true,"fullTextUrl":"/video/result?ask_summarization=1&numdoc=1&noreask=1&nomisspell=1&parent-reqid=1751312994907867-5927566633186481265-balancer-l7leveler-kubr-yp-vla-124-BAL&text=videoid:4259983989974865829","teaser":[{"list":{"type":"unordered","items":["Bu video, bir eğitmen tarafından sunulan eğitim dersi formatında olup, polimerlerin moleküler ağırlıkları ve mekanik özellikleri konusunu ele almaktadır.","Ders, polimerlerin moleküler ağırlıklarının fiziksel, kimyasal ve mekanik özelliklerini nasıl etkilediğini açıklamaktadır. Eğitmen, polimerizasyon derecesinin ortalama olduğu, molekül ağırlığının erime noktaları, camsı geçiş sıcaklıkları, viskozite, çekme gerilimi ve kopma dayanımı gibi mekanik özelliklere etkisini örneklerle anlatmaktadır.","Dersin sonunda, bir sonraki derste molekül ağırlığı belirleme yöntemlerine giriş yapılacağı ve GPS konusuna odaklanılacağı bilgisi verilmektedir. Ayrıca, polimerlerin en iyi işlenebilirlik aralıkları da açıklanmaktadır."]},"endTime":1411,"title":"Polimerlerin Moleküler Ağırlıkları ve Mekanik Özellikleri Dersi","beginTime":0}],"fullResult":[{"index":0,"title":"Polimerlerin Moleküler Ağırlıkları","list":{"type":"unordered","items":["Bu haftaki konu polimerlerin moleküler ağırlıkları, polimerizasyon derecesi ve polidisperse indeksi hakkında bilgi verecek.","Polimerlerin karakterize edilmesinde molekül ağırlığının öncelikle iyi tespit edilmesi gerekiyor çünkü bu özellik camsı geçiş sıcaklığı, erime sıcaklığı ve mekanik özelliklerini etkiliyor.","Polimerler, monomerlerin kovalent bağlarla birleşerek oluşturduğu yüksek mol kütleli bileşiklerdir ve makro moleküller olarak adlandırılır."]},"beginTime":0,"endTime":119,"href":"/video/preview/4259983989974865829?channelId=cnV0dWJlLnJ1OzMzOTE5MjI1&how=tm&parent-reqid=1751312994907867-5927566633186481265-balancer-l7leveler-kubr-yp-vla-124-BAL&text=%D0%9C%D0%B8%D0%BD%D0%B8%D0%BC%D0%B0%D0%BB%D0%B8%D1%81%D1%82%D0%B8%D1%87%D0%B5%D1%81%D0%BA%D0%BE%D0%B5+%D0%A1%D0%B8%D1%8F%D0%BD%D0%B8%D0%B5&t=0&ask_summarization=1"},{"index":1,"title":"Polimer Zincirlerinin Özellikleri","list":{"type":"unordered","items":["Polimer sentezi sırasında başlatıcıyı 1'e 100 oranında kullanırsak, polimerizasyon derecesi 100 olan bir polimer elde etmek istiyoruz.","Mol hesabından dolayı, ortamda Avogadro sayısı kadar tanecik olduğu için binlerce, milyonlarca polimer zinciri oluşur ve bu zincirler eşit uzunlukta değildir.","Polimerlerin molekül ağırlıkları ve polimerizasyon dereceleri ortalama olarak tanımlanır çünkü sentetik olarak üretilen hiçbir polimerin zincirleri birbirine eşit değildir."]},"beginTime":119,"endTime":221,"href":"/video/preview/4259983989974865829?channelId=cnV0dWJlLnJ1OzMzOTE5MjI1&how=tm&parent-reqid=1751312994907867-5927566633186481265-balancer-l7leveler-kubr-yp-vla-124-BAL&text=%D0%9C%D0%B8%D0%BD%D0%B8%D0%BC%D0%B0%D0%BB%D0%B8%D1%81%D1%82%D0%B8%D1%87%D0%B5%D1%81%D0%BA%D0%BE%D0%B5+%D0%A1%D0%B8%D1%8F%D0%BD%D0%B8%D0%B5&t=119&ask_summarization=1"},{"index":2,"title":"Moleküler Ağırlığın Önemi","list":{"type":"unordered","items":["Moleküler ağırlık, polimerin kullanım yerini belirler ve fiziksel, kimyasal ve mekanik özellikleri önemli derecede etkiler.","Moleküler ağırlığın artması, polimerler arasındaki moleküller arası çekim kuvvetlerinin artması ve polimerlerin temel özelliklerini belirleyen uzun zincirlerin oluşmasını sağlar.","Moleküler ağırlık, çözünme davranışları, mekanik özellikler, ısıl özellikler ve korozif özelliklere etki eder."]},"beginTime":221,"endTime":323,"href":"/video/preview/4259983989974865829?channelId=cnV0dWJlLnJ1OzMzOTE5MjI1&how=tm&parent-reqid=1751312994907867-5927566633186481265-balancer-l7leveler-kubr-yp-vla-124-BAL&text=%D0%9C%D0%B8%D0%BD%D0%B8%D0%BC%D0%B0%D0%BB%D0%B8%D1%81%D1%82%D0%B8%D1%87%D0%B5%D1%81%D0%BA%D0%BE%D0%B5+%D0%A1%D0%B8%D1%8F%D0%BD%D0%B8%D0%B5&t=221&ask_summarization=1"},{"index":3,"title":"Moleküler Ağırlığın Fiziksel Özelliklere Etkisi","list":{"type":"unordered","items":["Moleküler ağırlık arttıkça polimerlerin çözünürlükleri genellikle düşer; örneğin, küçük moleküllü polietilen glikol 20 derecede çözünürken, daha yüksek mol kütleli olanları daha yüksek sıcaklıkta çözünür.","Moleküler ağırlık arttıkça camsı geçiş sıcaklığı (Tg) ve erime sıcaklığı artar; Tg'nin üzerinde polimer yumuşak, Tg'nin altında ise sert bir durum gösterir.","Moleküler ağırlık arttıkça erik viskozite de artar; başlangıçta yavaş artan viskozite daha sonra hızlanır ve polimerin akışkan olması için ideal viskoziteyi aştığında işleme ve kalıplama zorluğu ortaya çıkar."]},"beginTime":323,"endTime":562,"href":"/video/preview/4259983989974865829?channelId=cnV0dWJlLnJ1OzMzOTE5MjI1&how=tm&parent-reqid=1751312994907867-5927566633186481265-balancer-l7leveler-kubr-yp-vla-124-BAL&text=%D0%9C%D0%B8%D0%BD%D0%B8%D0%BC%D0%B0%D0%BB%D0%B8%D1%81%D1%82%D0%B8%D1%87%D0%B5%D1%81%D0%BA%D0%BE%D0%B5+%D0%A1%D0%B8%D1%8F%D0%BD%D0%B8%D0%B5&t=323&ask_summarization=1"},{"index":4,"title":"Karbon Sayısının Fiziksel Hal Üzerindeki Etkisi","list":{"type":"unordered","items":["Karbon sayısı 5-6 aralığında polimerler sıvı yapıda, 6-9 aralığında düşük viskoziteli sıvı, 9-16 aralığında orta viskoziteli sıvı oluşturur.","16-25 aralığında mumsu davranış gösteren sıvı katı formu oluşur, 25-50 aralığında parafinler oluşur ve bu noktadan sonrası yüksek mol kütleli polimerlerdir.","Karbon sayısı arttıkça erime noktaları değişir ve bu da polimerin fiziksel haline etki eder; sıvı parafinlerden katı parafinlere geçişte erime noktalarında artış görülür."]},"beginTime":562,"endTime":723,"href":"/video/preview/4259983989974865829?channelId=cnV0dWJlLnJ1OzMzOTE5MjI1&how=tm&parent-reqid=1751312994907867-5927566633186481265-balancer-l7leveler-kubr-yp-vla-124-BAL&text=%D0%9C%D0%B8%D0%BD%D0%B8%D0%BC%D0%B0%D0%BB%D0%B8%D1%81%D1%82%D0%B8%D1%87%D0%B5%D1%81%D0%BA%D0%BE%D0%B5+%D0%A1%D0%B8%D1%8F%D0%BD%D0%B8%D0%B5&t=562&ask_summarization=1"},{"index":5,"title":"Moleküler Ağırlığın Diğer Özelliklere Etkisi","list":{"type":"unordered","items":["Polimerizasyon derecesi, polimerdeki monomerin tekrar etme sayısıdır ve de ortalama olarak ifade edilir.","Polimerizasyon derecesi 2000 olan polietilenin moleküler ağırlığı, 28 tekrar eden birim olduğu için 56.000'dir.","Moleküler ağırlık arttıkça camsı geçiş sıcaklığı (Tg) ve erime sıcaklığı (Tm) artar; ancak bu artış 7000 civarından sonra yavaşlar veya durur.","Moleküler ağırlığın artışıyla Tg ve Tm sıcaklıkları sınırlı bir derecede değişir; bu değerlerin ayarlanması için plastikleştiriciler (Tg'yi düşüren katkı maddeleri) eklenir."]},"beginTime":723,"endTime":945,"href":"/video/preview/4259983989974865829?channelId=cnV0dWJlLnJ1OzMzOTE5MjI1&how=tm&parent-reqid=1751312994907867-5927566633186481265-balancer-l7leveler-kubr-yp-vla-124-BAL&text=%D0%9C%D0%B8%D0%BD%D0%B8%D0%BC%D0%B0%D0%BB%D0%B8%D1%81%D1%82%D0%B8%D1%87%D0%B5%D1%81%D0%BA%D0%BE%D0%B5+%D0%A1%D0%B8%D1%8F%D0%BD%D0%B8%D0%B5&t=723&ask_summarization=1"},{"index":6,"title":"Camsı Geçiş Sıcaklığı","list":{"type":"unordered","items":["Camsı geçiş sıcaklığı, polimerlerin titreşim ve dönme hareketlerinden konformasyon hareketlerine geçtiği sıcaklıktır.","Bu sıcaklıkta moleküller arası bağlarda gevşemeler ve kopmalar oluşarak polimer zincirleri eğilip bükülebilmekte ve polimer yumuşamaktadır.","Camsı geçiş sıcaklığına gelinmediğinde polimer sert, gelindiğinde ve üstünde ise yumuşaktır, bu erime olayı değildir."]},"beginTime":973,"endTime":1029,"href":"/video/preview/4259983989974865829?channelId=cnV0dWJlLnJ1OzMzOTE5MjI1&how=tm&parent-reqid=1751312994907867-5927566633186481265-balancer-l7leveler-kubr-yp-vla-124-BAL&text=%D0%9C%D0%B8%D0%BD%D0%B8%D0%BC%D0%B0%D0%BB%D0%B8%D1%81%D1%82%D0%B8%D1%87%D0%B5%D1%81%D0%BA%D0%BE%D0%B5+%D0%A1%D0%B8%D1%8F%D0%BD%D0%B8%D0%B5&t=973&ask_summarization=1"},{"index":7,"title":"Polimerlerin Molekül Ağırlığına Göre Mekanik Özellikleri","list":{"type":"unordered","items":["Polimerlerin mekanik özellikleri molekül ağırlığından etkilenmektedir.","Çekme ve çarpma direnci ilk başlarda hızlı, sonra yavaşlayarak, 10 üzeri 6'dan sonra iyice yavaşlayarak artarken, erime viskozitesi ilk başta yavaş, 10 üzeri 4-6 arasında orta seviyede, 10 üzeri 6'dan sonra hızlı artmaktadır.","Polimerlerin tüm özellikleri molekül ağırlığıyla aynı şekilde değişmez, bazıları sınıra sahipken bazıları sınır olmadan artmaktadır."]},"beginTime":1029,"endTime":1127,"href":"/video/preview/4259983989974865829?channelId=cnV0dWJlLnJ1OzMzOTE5MjI1&how=tm&parent-reqid=1751312994907867-5927566633186481265-balancer-l7leveler-kubr-yp-vla-124-BAL&text=%D0%9C%D0%B8%D0%BD%D0%B8%D0%BC%D0%B0%D0%BB%D0%B8%D1%81%D1%82%D0%B8%D1%87%D0%B5%D1%81%D0%BA%D0%BE%D0%B5+%D0%A1%D0%B8%D1%8F%D0%BD%D0%B8%D0%B5&t=1029&ask_summarization=1"},{"index":8,"title":"Mukavemet ve Molekül Ağırlığı","list":{"type":"unordered","items":["Polimerlerin mukavemeti molekül ağırlığıyla ilişkilendirilse de, ana iskelet ve yan gruplardaki gruplar da mukavemetin temelini oluşturur.","Polimerlerin en iyi işlenebilirliği ve mukavemet gösterdiği aralık genellikle 10.000 ile 100.000 veya 5.000 ile 10.000 arasında bulunmaktadır.","Moleküllerin kendi aralarındaki bağları, polimerlerin mukavemetini etkiler."]},"beginTime":1127,"endTime":1216,"href":"/video/preview/4259983989974865829?channelId=cnV0dWJlLnJ1OzMzOTE5MjI1&how=tm&parent-reqid=1751312994907867-5927566633186481265-balancer-l7leveler-kubr-yp-vla-124-BAL&text=%D0%9C%D0%B8%D0%BD%D0%B8%D0%BC%D0%B0%D0%BB%D0%B8%D1%81%D1%82%D0%B8%D1%87%D0%B5%D1%81%D0%BA%D0%BE%D0%B5+%D0%A1%D0%B8%D1%8F%D0%BD%D0%B8%D0%B5&t=1127&ask_summarization=1"},{"index":9,"title":"Polimer Yapısının Etkileri","list":{"type":"unordered","items":["Polyester yapısında dipol etkileşimleri (negatif-positif) bulunurken, poliamid yapısında hidrojen bağı oluşabilir.","Hidrojen bağı, dipol-dipol etkileşiminden daha kuvvetli olduğundan, poliamidlerin genel olarak mukavemeti ve ısıl dayanımı daha iyi olur."]},"beginTime":1216,"endTime":1268,"href":"/video/preview/4259983989974865829?channelId=cnV0dWJlLnJ1OzMzOTE5MjI1&how=tm&parent-reqid=1751312994907867-5927566633186481265-balancer-l7leveler-kubr-yp-vla-124-BAL&text=%D0%9C%D0%B8%D0%BD%D0%B8%D0%BC%D0%B0%D0%BB%D0%B8%D1%81%D1%82%D0%B8%D1%87%D0%B5%D1%81%D0%BA%D0%BE%D0%B5+%D0%A1%D0%B8%D1%8F%D0%BD%D0%B8%D0%B5&t=1216&ask_summarization=1"},{"index":10,"title":"Polimer Özelliklerinin Özeti","list":{"type":"unordered","items":["Çekme gerilimi, kopma, uzama miktarı, akma dayanımı, sürekli kırılganlık, sertlik, erik viskozite, yapışma ve kimyasal dayanıklılık gibi özellikler molekül ağırlığı arttıkça genellikle artarken, yapışma ve çözünürlük azalmaktadır.","PD (polimer dağılımı) değeri, polimer zincirlerinin eşit uzunlukta olmamasını ifade eder; 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